28 Sep The Definitive Guide to Saturated Fatty Acids
What are saturated fats, exactly? Today, I’m diving into the nuances of saturated fatty acids — a guide to all the individual fatty acids that make up the saturated fats we eat, store, and burn.
I won’t cover every single saturated fatty acid in existence. Some don’t play any significant role in human health or diet, like cerotic acid, which appears mainly in beeswax. Or arachidic acid, which you can get by hydrogenating arachidonic acid or eating a ton of durian fruit. There are a few more that aren’t very relevant.
I will instead cover the most important ones.
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Saturated Fat Definition
A fatty acid molecule is typically an arrangement of carbon and hyrdrogen atoms. Saturated fats have two main characteristics:
- All or most of the carbon-hydrogen bonds are single bonds
- All available carbon bonds are paired with hydrogen atoms
This makes saturated fats highly stable and resistant to oxidation and rancidity, even when heated. That’s why our bodies tend to build cellular membranes with a significant portion of saturated fats. They provide stability and a strong foundation.
The 5 Main Categories of Saturated Fats
Saturated fats you most commonly see in the human diet include:
- Caproic acid, caprylic acid, and capric acid
- Lauric acid
- Myristic acid
- Stearic acid
- Palmitic acid
Again, there are a few other categories of saturated fats that aren’t as relevant to the human diet, so I’m covering the most important ones.
1. Caproic Acid, Caprylic Acid and Capric Acid
Caproic acid, caprylic acid, and capric acid are all medium-chain triglycerides, which means the fatty acid molecule has a tail length of 6-12 carbon atoms. Short-chain fatty acids have fewer than 6 carbon atoms, and long-chain saturated fats have more than 12.
I included these together because their names come from the Latin word for “goat,” and all three are found most famously in goat milk — they run about 15% of goat milk fat. You can also find capric acid in smaller amounts in coconut oil (10% of coconut fat) and palm oil (4% of palm fat).
The “goat” fats are what give goat milk its distinctive “goaty” odors. Come to think of it, I’ve had coconut oil that had a “funk” to it, and I bet the capric and caprylic acids were to blame. But if you can get past the goatiness, there are benefits to these fatty acids.
- Capric acid has been used to inhibit seizures in people with epilepsy,https://www.ncbi.nlm.nih.gov/pubmed/25445478‘>2
- As medium-chain triglycerides, the goat fatty acids increase ketone production. In fact, caprylic acidhttps://todayspractitioner.com/alzheimers/caprylic-acid-shows-greater-plasma-ketone-response-in-humans-consuming-different-medium-chain-triglycerides/#.XjDlfhSYVBw‘>4
- Capric acid has anti-fungal properties, showing particular efficacy against Candida,https://www.ncbi.nlm.nih.gov/pubmed/21333271‘>6
Best sources of capric acid, caprylic acid, and caproic acid: goat milk, coconut oil, palm oil
2. Lauric Acid
Another medium-chain triglyceride, lauric acid is the primary fatty acid in coconut fat (40-50% lauric acid) and palm kernel fat. It also appears in human breast milk (about 6.2% of total fat).
- Lauric acid is anti-microbial. That’s why it appears in breast milk—to help infants ward off pathogens while their immune systems are still developing. And it’s probably why people report getting rid of foot and toenail fungus by smearing their feet with coconut oil.https://www.ncbi.nlm.nih.gov/pubmed/18469237‘>8
- When you consume lauric acid, some of it is converted into monolaurin, a more potent compound (both coconut oil and breast milk also contain some monolaurin directly) with anti-viral, anti-microbial, and anti-fungal properties.
- Lauric acid is not as directly ketogenic as the “goaty” medium-chain triglycerides.
Best sources of lauric acid: coconut fat, palm kernel fat, breast milk
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3. Myristic Acid
Myristic acid is a perplexing one. Some studies find that its presence in the blood indicates metabolic issues, whereas, as you’ll see below, in the diet it can have some good effects and play some important roles.https://www.ncbi.nlm.nih.gov/pubmed/30787402‘>10
It’s getting really tough to deny the benefits of stearic acid.
Best sources of stearic acid: cocoa butter, beef fat (steer/stearic), dairy, lard
5. Palmitic Acid
Palmitic acid gets a terrible rap. In study after study, we find palmitic acid doing bad things to our cells and our health markers. And when you douse cells in pure palmitic acid, they tend to suffer and even die. This looks really bad.
For instance, palmitic acid lowers expression of the LDL receptor gene.17 Less LDL receptor activity, more time for LDL to hang around in the bloodstream and cause trouble.http://www.ncbi.nlm.nih.gov/pubmed/21478880‘>19 and disrupts insulin signaling, suggestive of diabetes. We don’t want diabetes, we don’t want heart disease, and we like our muscle cells to function, so we should probably stop eating any palmitic acid, right?
Except a modicum of oleic acid stimulates LDL receptor activity.https://www.marksdailyapple.com/arachidonic-acid/‘>21 a polyunsaturated fat found in animal products often alongside palmitic acid, prevents cell toxicity.http://www.ncbi.nlm.nih.gov/pubmed/16126172‘>23
Okay, but what about serum palmitic acid being a harbinger of metabolic disorder? Easy. When you overeat sugar and there’s nowhere to put it and you can’t burn it, the liver converts any extra into palmitic acid to be stored. Elevated palmitic acid is a marker of eating too many carbohydrates (and food in general).
Best sources: dairy fat, ruminant fat, palm oil.
What does it all mean?
Even though today’s post was about the individual saturated fatty acids, we very rarely eat individual fatty acids. Instead, we’re eating fats that contain a half dozen fatty acids or more, or foods that contain fats that contain a half dozen fatty acids. We aren’t cooking with lauric acid or sprinkling pure palmitic acid in the pan. We’re eating foods. And, as part of the food matrix, all the saturated fatty acids I’ve examined have important and valid roles to play.
If you want to avoid palmitic acid but welcome stearic acid, guess what? You’re gonna have to craft some Frankenstein-fat. Foods that contain stearic acid also contain palmitic acid. The best sources of lauric acid are also pretty high in stearic, palmitic, and myristic acid. And so it goes. You can’t avoid palmitic acid and only eat lauric and stearic acid while eating actual food.
If you have any questions, drop them down below.
Thanks for reading, everyone!
References
- https://pubmed.ncbi.nlm.nih.gov/26608744-seizure-control-by-decanoic-acid-through-direct-ampa-receptor-inhibition/
- https://www.ncbi.nlm.nih.gov/pubmed/25445478
- https://todayspractitioner.com/alzheimers/caprylic-acid-shows-greater-plasma-ketone-response-in-humans-consuming-different-medium-chain-triglycerides/#.XjDlfhSYVBw
- https://todayspractitioner.com/alzheimers/caprylic-acid-shows-greater-plasma-ketone-response-in-humans-consuming-different-medium-chain-triglycerides/#.XjDlfhSYVBw
- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919387/
- https://www.ncbi.nlm.nih.gov/pubmed/21333271
- https://www.researchgate.net/profile/Gambhirsinh_Vala2/publication/280574942_Medicinal_Benefits_of_Coconut_Oil_A_Review_paper/links/55bb561b08ae092e965ed871/Medicinal-Benefits-of-Coconut-Oil-A-Review-paper.pdf
- https://www.ncbi.nlm.nih.gov/pubmed/18469237
-
https://www.ncbi.nlm.nih.gov/pubmed/22849318[/ref]
- The odor of myristic acid draws the newborn to the breast and helps trigger the appetite for mother’s milk.[ref]https://www.ncbi.nlm.nih.gov/pubmed/28886572
- https://www.ncbi.nlm.nih.gov/pubmed/30787402
- https://www.cambridge.org/core/journals/british-journal-of-nutrition/article/div-classtitlevariations-in-daily-intakes-of-myristic-and-linolenic-acids-in-sn-2-position-modify-lipid-profile-and-red-blood-cell-membrane-fluiditydiv/83AA3871CA89CDD1D0D48CC5B6019203
- https://www.marksdailyapple.com/dairy-fat-healthy-paleo-primal/
- https://www.ncbi.nlm.nih.gov/pubmed/7270479/
- https://www.ncbi.nlm.nih.gov/pubmed/19939984
- https://www.ncbi.nlm.nih.gov/pubmed/30087348
- https://www.ncbi.nlm.nih.gov/pubmed/26178720
- http://www.ncbi.nlm.nih.gov/pubmed/8978483
- https://www.marksdailyapple.com/the-straight-dope-on-cholesterol-10-things-you-need-to-know-part-2/
- http://www.ncbi.nlm.nih.gov/pubmed/21478880
- http://www.ncbi.nlm.nih.gov/pubmed/7730302
- https://www.marksdailyapple.com/arachidonic-acid/
- http://www.ncbi.nlm.nih.gov/pubmed/24521082
- http://www.ncbi.nlm.nih.gov/pubmed/16126172
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